The Catalytic Asymmetric Diels-Alder Reactions and Post-cycloaddition Reductive Transpositions of 1-Hydrazinodienes was written by Xie, Hao;Sammis, Glenn M.;Flamme, Eric M.;Kraml, Christina M.;Sorensen, Erik J.. And the article was included in Chemistry – A European Journal in 2011.Recommanded Product: 3-Acryloyloxazolidin-2-one This article mentions the following:
Chiral copper(II) bis(oxazoline) catalyzed regio- and stereoselective intermol. Diels-Alder reactions of 1-hydrazinodienes with various electron-deficient alkenes has been developed to yield multisubstituted cyclohexenes, e.g. I (R = H, Me, Ph, EtO2C). These products can then undergo a mild, post-cycloaddition stereoselective reductive rearrangement to give new cyclohexenes, e.g. II (R = H, Me, Ph). In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Recommanded Product: 3-Acryloyloxazolidin-2-one).
3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. In another report, the incorporation of an additional substituted oxazolidine ring over a range of new biphenylazepinium salt organocatalysts for the asymmetric epoxidation of alkenes improved enantiocontrol over the parent structures.Recommanded Product: 3-Acryloyloxazolidin-2-one
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem