The Absolute Best Science Experiment for Oxazolidin-2-one

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Substituted cis-hydrindan-4-ones by sequential cycloadditions

The synthesis of substituted cis-hydrindan-4-ones is reported. Particular emphasis was placed on the diastereoselective construction of quaternary stereogenic ring carbon atoms. An intermolecular asymmetric Al(III)-promoted (4+2)-cycloaddition served as the principal C/C-connecting tool. Opportunities for the further structural elaboration of the (4+2)-cycloadducts were explored.

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Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H1022NO – PubChem