184363-66-4, Name is (S)-4-Phenyl-3-propionyloxazolidin-2-one, belongs to oxazolidine compound, is a common compound. category: oxazolidineIn an article, once mentioned the new application about 184363-66-4.
Direct alpha-siladifluoromethylation of lithium enolates with ruppert-prakash reagent via Ci-F bond activation
The direct alpha-siladifluoromethylation of lithium enolates with the Ruppert-Prakash reagent (CF3TMS) is shown to construct the tertiary and quaternary carbon centers. The Ruppert-Prakash reagent, which is versatile for various trifluoromethylation as a trifluoromethyl anion (CF3 -) equivalent, can be employed as a siladifluoromethyl cation (TMSCF2+) equivalent by Ci-F bond activation due to the strong interaction between lithium and fluorine atoms. Reaching for Ruppert-Prakash: The direct alpha-siladifluoromethylation of lithium enolates with the Ruppert-Prakash reagent (CF3TMS) is shown to construct tertiary and quaternary carbon centers (see scheme). The Ruppert-Prakash reagent can be employed as a siladifluoromethyl cation (TMSCF2+) equivalent by Ci-F bond activation due to the strong interaction between lithium and fluorine atoms.
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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H2262NO – PubChem