184346-45-0, Name is (S)-4-Isopropyl-5,5-diphenyloxazolidin-2-one, belongs to oxazolidine compound, is a common compound. COA of Formula: C18H19NO2In an article, once mentioned the new application about 184346-45-0.
(Equation Presented) The 3-methylthiomethyl-4-isopropyl-5,5-diphenyl-1,3-oxazolidin-2-one (I, prepared in three steps from Boc-valine ester) is lithiated and added to aldehydes, with protecting in situ trapping of the primary adducts, to give the N,S-acetal derivatives II of 2-hydroxy a dehydes in high yields and diastereoselectivities. Cleavage (with ready recovery of the oxazolidinone auxiliary) is possible, to afford, for instance, enantiopure 1,2-diols, selectively protected (OBn, OMOM, OTBS) in the 2-position.
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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H2631NO – PubChem