Tag: 141.1247

Huang, Lin et al. published their research in ACS Catalysis in 2015 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds are well-known chiral auxiliaries and strategic molecular moieties in chemistry since they can effectively mask or mimic amino acid units or amino alcohols. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Reference of 2043-21-2

Alkene Trifluoromethylation-Initiated Remote α-Azidation of Carbonyl Compounds toward Trifluoromethyl γ-Lactam and Spirobenzofuranone-Lactam was written by Huang, Lin;Lin, Jin-Shun;Tan, Bin;Liu, Xin-Yuan. And the article was included in ACS Catalysis in 2015.Reference of 2043-21-2 This article mentions the following:

The first unprecedented one-pot domino strategy toward diverse CF3-containing γ-lactam, e.g., I, and spirobenzofuranone-lactam scaffolds, e.g.,II, of antibacterial armeniaspirole from readily available acyclic precursors was developed. The key point of this transformation was the concurrent incorporation of CF3 and azide into the alkene and remote carbonyl α-C-H position via carbonyl-stabilized radical intermediate triggered by alkene trifluoromethylation via a 1,5-H shift in a highly controlled site-selective manner. Furthermore, gram-scale synthesis and synthetic applicability of these compounds proved suitable. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Reference of 2043-21-2).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds are well-known chiral auxiliaries and strategic molecular moieties in chemistry since they can effectively mask or mimic amino acid units or amino alcohols. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Reference of 2043-21-2

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Lerum, Ronald V. et al. published their research in Advanced Synthesis & Catalysis in 2013 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. A common way to produce multisubstituted oxazolidines is by means of cycloaddition reactions. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Application In Synthesis of 3-Acryloyloxazolidin-2-one

A Rhodium-Catalyzed Tandem Alkyne Dimerization/1,4-Addition Reaction was written by Lerum, Ronald V.;Russo, Christopher M.;Marquez, Jocellie E.;Chisholm, John D.. And the article was included in Advanced Synthesis & Catalysis in 2013.Application In Synthesis of 3-Acryloyloxazolidin-2-one This article mentions the following:

A convenient three-component coupling reaction for the construction of conjugated enynes using rhodium catalysis is reported. Dimerization of a monosubstituted alkyne followed by trapping of the vinyl metal intermediate with an electron-deficient alkene, such as Me vinyl ketone, provided moderate to good yields of these enynes. The use of the hindered electron-rich tris(ortho-tolyl)phosphine as a ligand for the rhodium catalyst provided the best conversions to these complex products. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Application In Synthesis of 3-Acryloyloxazolidin-2-one).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. A common way to produce multisubstituted oxazolidines is by means of cycloaddition reactions. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Application In Synthesis of 3-Acryloyloxazolidin-2-one

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Ito, Hisanaka et al. published their research in Tetrahedron in 2005 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds are well-known chiral auxiliaries and strategic molecular moieties in chemistry since they can effectively mask or mimic amino acid units or amino alcohols. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.Safety of 3-Acryloyloxazolidin-2-one

Lewis acid promoted reactions of γ,γ-dialkoxyallylic zirconium species with various carbonyl compounds was written by Ito, Hisanaka;Sato, Azusa;Taguchi, Takeo. And the article was included in Tetrahedron in 2005.Safety of 3-Acryloyloxazolidin-2-one This article mentions the following:

The reactions of γ,γ-dialkoxyallylic zirconium species with carbonyl compounds in the presence of Lewis acid are reported. The reactivity of γ,γ-dialkoxyallylic zirconium species and reaction pathway were strongly dependent on the structure and electrostatic nature of the carbonyl compounds In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Safety of 3-Acryloyloxazolidin-2-one).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds are well-known chiral auxiliaries and strategic molecular moieties in chemistry since they can effectively mask or mimic amino acid units or amino alcohols. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.Safety of 3-Acryloyloxazolidin-2-one

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Xie, Hao et al. published their research in Chemistry – A European Journal in 2011 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. In another report, the incorporation of an additional substituted oxazolidine ring over a range of new biphenylazepinium salt organocatalysts for the asymmetric epoxidation of alkenes improved enantiocontrol over the parent structures.Recommanded Product: 3-Acryloyloxazolidin-2-one

The Catalytic Asymmetric Diels-Alder Reactions and Post-cycloaddition Reductive Transpositions of 1-Hydrazinodienes was written by Xie, Hao;Sammis, Glenn M.;Flamme, Eric M.;Kraml, Christina M.;Sorensen, Erik J.. And the article was included in Chemistry – A European Journal in 2011.Recommanded Product: 3-Acryloyloxazolidin-2-one This article mentions the following:

Chiral copper(II) bis(oxazoline) catalyzed regio- and stereoselective intermol. Diels-Alder reactions of 1-hydrazinodienes with various electron-deficient alkenes has been developed to yield multisubstituted cyclohexenes, e.g. I (R = H, Me, Ph, EtO2C). These products can then undergo a mild, post-cycloaddition stereoselective reductive rearrangement to give new cyclohexenes, e.g. II (R = H, Me, Ph). In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Recommanded Product: 3-Acryloyloxazolidin-2-one).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. In another report, the incorporation of an additional substituted oxazolidine ring over a range of new biphenylazepinium salt organocatalysts for the asymmetric epoxidation of alkenes improved enantiocontrol over the parent structures.Recommanded Product: 3-Acryloyloxazolidin-2-one

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Caleffi, Guilherme S. et al. published their research in Journal of Organic Chemistry in 2019 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Oxazolidines are commonly used as metal ligands in asymmetric catalysis, synthetic intermediates in organic synthesis, and also used as the protecting groups.Name: 3-Acryloyloxazolidin-2-one

Switching Diastereoselectivity in Catalytic Enantioselective (3+2) Cycloadditions of Azomethine Ylides Promoted by Metal Salts and Privileged Segphos-Derived Ligands was written by Caleffi, Guilherme S.;Larranaga, Olatz;Ferrandiz-Saperas, Marcos;Costa, Paulo R. R.;Najera, Carmen;de Cozar, Abel;Cossio, Fernando P.;Sansano, Jose M.. And the article was included in Journal of Organic Chemistry in 2019.Name: 3-Acryloyloxazolidin-2-one This article mentions the following:

Catalytic enantioselective 1,3-dipolar cycloaddition between imino esters and electrophilic alkenes, employing chiral metal complexes derived from copper(I) and silver(I) salts and (S)-DM- or (S)-DTBM-Segphos as ligands produces diastereodivergently exo- or endo-cycloadducts, resp. The effect of the functional group of the dipolarophile and the fine tuning of the catalyst plays an important role in promoting reverse diastereoselectivities. The origins of exptl. observed enantioselectivity and diastereoselectivity data, as well as the origin of the observed switched endo/exo ratios, are also explained by means of d. functional theory calculations In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Name: 3-Acryloyloxazolidin-2-one).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Oxazolidines are commonly used as metal ligands in asymmetric catalysis, synthetic intermediates in organic synthesis, and also used as the protecting groups.Name: 3-Acryloyloxazolidin-2-one

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Valli, Matteo et al. published their research in Journal of Organic Chemistry in 2014 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. Oxazolidines are commonly used as metal ligands in asymmetric catalysis, synthetic intermediates in organic synthesis, and also used as the protecting groups.Computed Properties of C6H7NO3

A Unified Stereodivergent Strategy for Prostaglandin and Isoprostanoid Synthesis was written by Valli, Matteo;Chiesa, Francesco;Gandini, Andrea;Porta, Alessio;Vidari, Giovanni;Zanoni, Giuseppe. And the article was included in Journal of Organic Chemistry in 2014.Computed Properties of C6H7NO3 This article mentions the following:

Acetoxyfulvene I surrendered to asym. Diels-Alder cycloaddition, paving the way to the development of a unified strategy for the stereodivergent synthesis of both prostaglandins and isoprostanoids. In fact, the cycloadduct II was subsequently converted to a common intermediate, which through two different stereoselective pathways afforded the two lactones III and IV, which are key building blocks in the synthesis of prostaglandins and isoprostanoids, resp. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Computed Properties of C6H7NO3).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. Oxazolidines are commonly used as metal ligands in asymmetric catalysis, synthetic intermediates in organic synthesis, and also used as the protecting groups.Computed Properties of C6H7NO3

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Argyropoulos, Nikolaos G. et al. published their research in Tetrahedron in 2007 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Some reports highlighted again the effectiveness of oxazolidine-based compounds in driving the stereo- or diastereotopic outcome of chemical reactions.HPLC of Formula: 2043-21-2

Asymmetric nitrone cycloadditions and their application to the synthesis of enantiopure pyrrolidine and pyrrolizidine derivatives was written by Argyropoulos, Nikolaos G.;Panagiotidis, Theodoros;Coutouli-Argyropoulou, Evdoxia;Raptopoulou, Catherine. And the article was included in Tetrahedron in 2007.HPLC of Formula: 2043-21-2 This article mentions the following:

The cycloaddition reactions of a pair of chiral pyrroline-N-oxides derived from D-ribose, e.g. I, with some typical mono- and disubstituted alkenes are reported. In all these reactions with monosubstituted alkenes as well as with di-Me maleate the preferred stereochem. outcome of the cycloaddition step comes from a 5-exo-anti transition state whereas stereoisomers from the 5-exo-syn transition state are also present as minor adducts. In the reaction with di-Me fumarate the major adduct comes from a 4-exo-5-endo-syn transition state. The further behavior of the obtained isoxazolidines, e.g. II [R = EtO, MeO2C, (2-oxooxazolidin-3-yl)carbonyl], upon reductive ring opening conditions depends on the kind and the geometry of the preexisting substituents and they are transformed to enantiomerically pure pyrrolidine or pyrrolizidinone derivatives In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2HPLC of Formula: 2043-21-2).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Some reports highlighted again the effectiveness of oxazolidine-based compounds in driving the stereo- or diastereotopic outcome of chemical reactions.HPLC of Formula: 2043-21-2

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Sarma, Diganta et al. published their research in Applied Catalysis, A: General in 2008 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.HPLC of Formula: 2043-21-2

Rare earth metal triflates promoted Diels-Alder reactions in ionic liquids was written by Sarma, Diganta;Kumar, Anil. And the article was included in Applied Catalysis, A: General in 2008.HPLC of Formula: 2043-21-2 This article mentions the following:

Rare earth metal triflates, when used with ionic liquids can promote Diels-Alder reactions of dienes and dienophiles, where the catalytic activity of the triflates is enhanced by ionic liquids It is possible to recover and reuse the ionic liquid phase with triflates to give comparable yields and stereoselectivity even after six cycles. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2HPLC of Formula: 2043-21-2).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.HPLC of Formula: 2043-21-2

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Takahashi, Kouichi et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2007 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Product Details of 2043-21-2

Reuse of chiral cationic Pd-phosphinooxazolidine catalysts in ionic liquids: highly efficient catalytic asymmetric Diels-Alder reactions was written by Takahashi, Kouichi;Nakano, Hiroto;Fujita, Reiko. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2007.Product Details of 2043-21-2 This article mentions the following:

Chiral cationic palladium-phosphinooxazolidine catalysts in ionic liquid afforded excellent enantioselectivity in Diels-Alder reactions of cyclic dienes with β-(un)substituted N-acryloyl 2-oxazolidinones, and the catalyst was easily recycled eight times without any significant decrease in chem. yields or enantioselectivity (89-99% yields, 88-99% ee). In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Product Details of 2043-21-2).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Product Details of 2043-21-2

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Takahashi, Kouichi et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2007 | CAS: 2043-21-2

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Product Details of 2043-21-2

Reuse of chiral cationic Pd-phosphinooxazolidine catalysts in ionic liquids: highly efficient catalytic asymmetric Diels-Alder reactions was written by Takahashi, Kouichi;Nakano, Hiroto;Fujita, Reiko. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2007.Product Details of 2043-21-2 This article mentions the following:

Chiral cationic palladium-phosphinooxazolidine catalysts in ionic liquid afforded excellent enantioselectivity in Diels-Alder reactions of cyclic dienes with β-(un)substituted N-acryloyl 2-oxazolidinones, and the catalyst was easily recycled eight times without any significant decrease in chem. yields or enantioselectivity (89-99% yields, 88-99% ee). In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Product Details of 2043-21-2).

3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Product Details of 2043-21-2

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem