Highly Enantioselective and Diastereoselective 1,3-Dipolar Cycloaddition Reactions between Azomethine Imines and 3-Acryloyl-2-oxazolidinone Catalyzed by Binaphthyldiimine-Ni(II) Complexes was written by Suga, Hiroyuki;Funyu, Akira;Kakehi, Akikazu. And the article was included in Organic Letters in 2007.Related Products of 2043-21-2 This article mentions the following:
The first examples of high levels of asym. induction (97-74% ee) along with high diastereoselectivities (>99:1-64:36) in dipole-HOMO-/dipolarophile-LUMO-controlled asym. 1,3-dipolar cycloaddn between azomethine imines and 3-acryloyl-2-oxazolidinone were reported. Fused pyrazole derivatives I were synthesized by using a chiral BINIM-Ni(II) complex as a chiral Lewis acid catalyst. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Related Products of 2043-21-2).
3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries. Some reports highlighted again the effectiveness of oxazolidine-based compounds in driving the stereo- or diastereotopic outcome of chemical reactions.Related Products of 2043-21-2
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem