The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Oxazole( cas:288-42-6 ) is researched.Name: Oxazole.Qian, Lu; Tang, Xixia; Huang, Zhidao; Wang, Yulei; Liu, Guixia; Huang, Zheng published the article 《Chiral Iridium Complexes of Anionic NCP Pincer Ligand for Asymmetric Transfer Hydrogenation of 1,1-Diarylethenes with Ethanol》 about this compound( cas:288-42-6 ) in Organic Letters. Keywords: oxazolinylphosphinoxyphenyl iridium pincer complex preparation catalyst asym hydrogenation arylethene; crystal structure oxazolinylphosphinoxyphenyl iridium pincer complex bromophenylmethoxyphenylethane; mol structure oxazolinylphosphinoxyphenyl iridium pincer complex bromophenylmethoxyphenylethane. Let’s learn more about this compound (cas:288-42-6).
Chiral Ir complexes ligated by anionic oxazoline-bearing NCP-type pincer ligands were developed and applied to the asym. transfer hydrogenation (ATH) of diarylethenes using environmentally benign EtOH as the H donor. High enantioselectivities could be achieved for substrates bearing ortho-Me, ortho-Cl, or ortho-Br substituents on one of the aryl groups. The ATH of ortho-Br-substituted diarylethenes is particularly attractive due to the propensity of the C(aryl)-Br bond to undergo various new bond-forming events.
Different reactions of this compound(Oxazole)Name: Oxazole require different conditions, so the reaction conditions are very important.
Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem