Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. SDS of cas: 102029-44-7. Introducing a new discovery about 102029-44-7, Name is (R)-4-Benzyl-2-oxazolidinone
Remarkable dependence of the regioselectivity of free radical additions to 3-cinnamoyloxazolidin-2-ones on the stability of the intermediate adduct-radical, electrophilicity of the adding radicals and the conditions for their generation
Electrophilic (CCl3) and nucleophilic radicals (Pri) are found to add at 80C to the C=C bond of 3-(E)-cinnamoyl-4-phenyloxazolidin-2-one 1a and 3-(E)-cinnamoyl-4-benzyloxazolidin-2-one 1b predominantly at the alpha-position of the bond. While for the CCl3 radical no product of beta-addition has been found, for the Pri radical such a path constitutes up to 40% of the whole process at 80C. An interplay between the stability of the intermediate adduct radicals and the electrophilicity or nucleophilicity of the radicals undergoing addition are invoked to rationalize the observation. At a low temperature (-23C) beta-addition of the Pri radical becomes the dominant process (up to 75%).
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.SDS of cas: 102029-44-7, you can also check out more blogs about102029-44-7
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2048NO – PubChem