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Preparation and Complex Formation of Polymers Anchoring 2-Oxazolidinone
Polymers anchoring 3-unsubstituted 2-oxazolidinone were prepared and their complex formation with phenol and mercury(II) acetate were investigated.Preformed poly(4-hydroxystyrene) was treated with tris(2,3-epoxypropyl)isocyanurate to give a polymer containing 2-oxazolidinone residues within the limits of 57.7 molpercent.Polymers carrying 2-oxazolidinone were also prepared through the homopolymerization and copolymerization of 4-(2-oxo-5-oxazolidinylmethoxy)phenyl acrylate.The effective concentration of 2-oxazolidinone residue in the polymers, which is accessible to phenol, was determined on the assumption that the polymer-bound 2-oxazolidinone and phenol formed a 1:1 complex. 2-Oxazolidinone and a mercury atom formed a 2:1 complex; this relation on the molar ratio applies to all forms of complexes between the mercury atom and the 2-oxazolidinone residue in the polymers.
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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H643NO – PubChem