Simple exploration of 1,3-Bis(4,5-dihydrooxazol-2-yl)benzene

Synthetic Route of 34052-90-9, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 34052-90-9.

Synthetic Route of 34052-90-9, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 34052-90-9, Name is 1,3-Bis(4,5-dihydrooxazol-2-yl)benzene, SMILES is C1(C2=NCCO2)=CC=CC(C3=NCCO3)=C1, belongs to oxazolidines compound. In a article, author is Sabet-Sarvestani, Hossein, introduce new discover of the category.

Understanding the mechanism, thermodynamic and kinetic features of the Kukhtin-Ramirez reaction in carbamate synthesis from carbon dioxide

In this article, thermodynamic and kinetic aspects of the Kukhtin-Ramirez reaction of the carbamate formation from carbon dioxide have been investigated in the presence of various phosphorous reagents (PRs), in the gas and solvent phases, theoretically. The obtained carbamate is a precursor for the synthesis of oxazolidine-2,4-dione as a biologically important compound. Two kinds of phosphorous reagents have been considered: type 1 is the PRs which have variable numbers of nitrogen atoms while, type 2 is composed of PRs without nitrogen atoms. By investigation of the local nucleophilicity indices (N-k) and steric exchange energy (dE), the reaction kinetics was studied in the presence of these kinds of PRs. It was illustrated that the steric repulsion between the lone pair electrons of the phosphorus atom and its bonded groups and the nucleophilicity character of this atom are impressive factors in the reaction kinetics. On the other hand, the analysis of stabilization energies associated with the donor-acceptor orbitals of the oxide forms of PRs (PORs) shows that the number of nitrogen atoms of the studied PRs have remarkable effects on the thermodynamics of the overall reaction. Finally, it has been shown that the obtained Delta E-Reaction by MPWB95 and B3LYP functionals, are in an acceptable correlation with the Mulliken atomic spin density (P-k(-)) of the phosphorous atom.

Synthetic Route of 34052-90-9, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 34052-90-9.

Reference:
Oxazolidine – Wikipedia,
,Oxazolidine | C3H7NO – PubChem