Liquid-liquid partition coefficients of β-diketonato complexes of chromium(III) and palladium(II) in dodecane/(water-methanol mixture) systems was written by Saitoh, Koichi;Tsukahara, Satoshi;Suzuki, Nobuo. And the article was included in Analytical Letters in 1988.Application In Synthesis of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) This article mentions the following:
Liquid-liquid partition coefficients (KD) of both Cr(III) and Pd(II) complexes of several β-diketones between dodecane and a aqueous MeOH mixture were determined by a combined batch technique and high performance liquid chromatog. method. The KD of each metal complex is enhanced as the MeOH content of the liquid mixture decreases. In both homologs of the Cr(III) complexes and the Pd(II) complexes, the KD increases with an increase in mol. size of the complex, although the Cr(III) complex tends to have a smaller KD than the Pd(II) complex whose mol. size is comparable with that of the Cr complex. In the experiment, the researchers used many compounds, for example, Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1Application In Synthesis of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)).
Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.Application In Synthesis of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem