Because a catalyst decreases the height of the energy barrier, 108149-65-1, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.108149-65-1, Name is (S)-tert-Butyl 4-(hydroxymethyl)-2,2-dimethyloxazolidine-3-carboxylate, molecular formula is C11H21NO4. In a article£¬once mentioned of 108149-65-1
Generating Stereodiversity: Diastereoselective Fluorination and Highly Diastereoselective Epimerization of alpha-Amino Acid Building Blocks
Diastereoselective fluorination of N-Boc (R)- and (S)-2,2-dimethyl-4-((arylsulfonyl)methyl)oxazolidines and a previously unknown diastereoselective epimerization at the fluorine-bearing carbon atom alpha to the sulfone was realized. Diastereoselectivities of both reactions were excellent for benzothiazolyl sulfones, allowing access to two enantiomerically pure diastereomers from one chiral precursor. To demonstrate synthetic utility, the benzothiazolyl sulfones were converted to diastereomerically pure (S,S)- and (R,S)-benzyl sulfones via sulfinate salts and to amino acids. To understand the diastereoselectivities, DFT analysis was performed.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 108149-65-1 is helpful to your research. 108149-65-1
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2318NO – PubChem