Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Application In Synthesis of (R)-4-Benzyl-2-oxazolidinone. Introducing a new discovery about 102029-44-7, Name is (R)-4-Benzyl-2-oxazolidinone
The lyconadins: Enantioselective total syntheses of (+)-lyconadin A and (-)-lyconadin B
A full account of the enantioselective total syntheses of (+)-lyconadin A (1) and (-)-lyconadin B (2) is presented. Central to this venture was recognition and deployment of a key strategy-level intramolecular aldol/conjugate addition cascade that led, in a single operation, to two new carbon-carbon sigma-bonds, three new stereogenic centers, and two new rings, albeit with the incorrect stereogenicity at C(12) for the lyconadins. Correction of the C(12) stereogenicity was achieved via innovative use of a protonated intramolecular aminal. An aminoiodo olefin cyclization, in conjunction with alpha-pyridinone and 3,4-dihydropyridinone annulation protocols, permitted completion of the syntheses of (+)-lyconadin A (1) and (-)-lyconadin B (2), respectively.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Application In Synthesis of (R)-4-Benzyl-2-oxazolidinone, you can also check out more blogs about102029-44-7
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H1733NO – PubChem