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An efficient synthetic route is described to the gamma-lactone 11 corresponding to the dipeptide isostere (2S,4S,5S)-5-amino-6-cyclohexyl-4-hydroxy-2-isopropylhexanoic acid, in which stereochemical control is achieved by participation of chiral acyloxazolidinone 6 in a stereoselective bromolactonisation reaction.
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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H2581NO – PubChem