Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Recommanded Product: 184363-66-4. Introducing a new discovery about 184363-66-4, Name is (S)-4-Phenyl-3-propionyloxazolidin-2-one
Novel approach to stereoselective synthesis of (E)/(Z)-(N-acyl-oxazolidinone)-eneglycinates
(E)-(N-Acyl-oxazolidinone)-eneglycinates were synthesized with high stereoselectivity and in good yield by condensation of aldehydes with glycinates. (Z)-Eneglycinates could be prepared in high purity and moderate yield by transformation of (E)-eneglycinates under mild conditions. The effect on the (E)/(Z)-configuration of eneglycinates of steric hindrance by I¡À-substituents on the aldehyde was also examined. The software MMFF94 was used to explain the transformation of the thermodynamic product into the kinetic product and a plausible mechanism is given.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 184363-66-4, you can also check out more blogs about184363-66-4
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2271NO – PubChem