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A novel chalcogen-mediated oxyfunctionalization mode of ynamides for the synthesis of alpha-chalcogenyl acrylamides has been developed. Independent of metal catalysts, external oxidants and additives, this mild process afforded a range of structurally diverse alpha-chalcogenyl acrylamides, including alpha-selanyl acrylamides and alpha-tellanyl acrylamides. Interestingly, diverse ynamides tolerated in this approach gave different stereoselectivities.

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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H624NO – PubChem