X-ray photoelectron study of electron density distribution in palladium(II) β-diketonate complexes was written by Mazalov, L. N.;Trubina, S. V.;Kryuchkova, N. A.;Tarasenko, O. A.;Trubin, S. V.;Zharkova, G. I.. And the article was included in Journal of Structural Chemistry in 2007.Application of 15214-66-1 This article mentions the following:
The electron d. distribution in Pd(II) β-diketonate complexes was studied by XPS and DFT-B3LYP method. Data about the electronic structure (effective charges, core level energies) of the compounds are compared with their thermodn. parameters (thermal stability, vaporization enthalpy). In mol. crystals of Pd(II) β-diketonates, the volatility of the complexes and vaporization enthalpy ΔH depend not only on van der Waals interactions, but also on electrostatic interactions of mols. in crystal. In the experiment, the researchers used many compounds, for example, Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1Application of 15214-66-1).
Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives. A common way to produce multisubstituted oxazolidines is by means of cycloaddition reactions. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Application of 15214-66-1
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem