A Rhodium-Catalyzed Tandem Alkyne Dimerization/1,4-Addition Reaction was written by Lerum, Ronald V.;Russo, Christopher M.;Marquez, Jocellie E.;Chisholm, John D.. And the article was included in Advanced Synthesis & Catalysis in 2013.Application In Synthesis of 3-Acryloyloxazolidin-2-one This article mentions the following:
A convenient three-component coupling reaction for the construction of conjugated enynes using rhodium catalysis is reported. Dimerization of a monosubstituted alkyne followed by trapping of the vinyl metal intermediate with an electron-deficient alkene, such as Me vinyl ketone, provided moderate to good yields of these enynes. The use of the hindered electron-rich tris(ortho-tolyl)phosphine as a ligand for the rhodium catalyst provided the best conversions to these complex products. In the experiment, the researchers used many compounds, for example, 3-Acryloyloxazolidin-2-one (cas: 2043-21-2Application In Synthesis of 3-Acryloyloxazolidin-2-one).
3-Acryloyloxazolidin-2-one (cas: 2043-21-2) belongs to oxazolidine derivatives. A common way to produce multisubstituted oxazolidines is by means of cycloaddition reactions. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Application In Synthesis of 3-Acryloyloxazolidin-2-one
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem