Kelly, Sean M.’s team published research in Organic Letters in 2017-06-02 | CAS: 4042-43-7

Organic Letters published new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (addnl. nucleophile class). 4042-43-7 belongs to class oxazolidine, name is (R)-4-Methyloxazolidin-2-one, and the molecular formula is C4H7NO2, Computed Properties of 4042-43-7.

Kelly, Sean M. published the artcileChemoselective Copper-Catalyzed Ullmann-Type Coupling of Oxazolidinones with Bromoiodoarenes, Computed Properties of 4042-43-7, the main research area is chemoselective copper catalyzed Ullmann coupling oxazolidinone bromoiodoarene.

We describe the highly selective copper-catalyzed Ullmann-type coupling of bromoiodoarenes with oxazolidinones. 3,4,7,8-Tetramethyl-1,10-phenanthroline (Me4Phen) was identified as an optimal ligand promoting the desired C-N bond formation, while minimizing the competitive bromo-iodo exchange pathway that leads to formation of iodo-substituted and bis-coupled side products. The developed method is highly selective with a >98:2 ratio of the bromo- vs. iodo-substituted compounds obtained in the isolated products.

Organic Letters published new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (addnl. nucleophile class). 4042-43-7 belongs to class oxazolidine, name is (R)-4-Methyloxazolidin-2-one, and the molecular formula is C4H7NO2, Computed Properties of 4042-43-7.

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem