Half-Sandwich Ruthenium Phenolate-Oxazoline Complexes: Experimental and Theoretical Studies in Catalytic Transfer Hydrogenation of Nitroarene was written by Jia, Wei-Guo; Ling, Shuo; Zhang, Hai-Ning; Sheng, En-Hong; Lee, Richmond. And the article was included in Organometallics on January 8,2018.Related Products of 163165-91-1 The following contents are mentioned in the article:
Five Ru complexes [Ru(p-cymene)LCl] containing phenolate-oxazoline ligands [LH = 2-(4,5-dihydrooxazol-2-yl)phenol (1), 2-(4-methyl-4,5-dihydrooxazol-2-yl)phenol (2); L = 2-(4-ethyl-4,5-dihydrooxazol-2-yl)phenol (3), 2-(4-phenyl-4,5-dihydrooxazol-2-yl)phenol (4), 2-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)phenol (5)] were synthesized and characterized. The solid-state structures of all Ru complexes were determined by single-crystal x-ray diffraction. The catalytic activities of these complexes in the transfer hydrogenation reaction of nitroarenes to anilines were studied. Aniline and their derivatives were obtained in good to excellent yields with iso-PrOH as the hydride source. The present protocol provides an environmentally benign synthetic method for the reduction of nitroarenes to anilines without employing harsh reaction conditions. Theor. studies employing d. functional theory were carried with the aim to propose a feasible reaction mechanism and to draw insights into the reactivity of the half-sandwich Ru catalyst. This study involved multiple reactions and reactants, such as 2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol (cas: 163165-91-1Related Products of 163165-91-1).
2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol (cas: 163165-91-1) belongs to oxazolidine derivatives. Oxazolidines are commonly obtained by reaction of strained heterocycles, mainly aziridines. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.Related Products of 163165-91-1
163165-91-1;2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol;The future of 163165-91-1;New trend of C11H13NO2;function of 163165-91-1