Synthesis and characterization of dialkyl[2-(2-phenolato)oxazolines] of gallium(III) and indium(III): crystal structure of [{InMe2(OC6H4-OxMe2)}2] was written by Ghoshal, Shamik; Wadawale, Amey; Jain, Vimal K.; Nethaji, Munirathinam. And the article was included in Journal of Chemical Research on April 30,2007.Category: oxazolidine The following contents are mentioned in the article:
Reactions of trialkylgallium and -indium etherates with 2-(2-hydroxyphenyl)oxazolines afforded colorless dialkyl[2-(2-phenolato)oxazoline]gallium and -indium complexes I and II (R = Me or Et; Ox = oxazoline, R’ = Me or Et; R” = Me or H). These complexes were characterized by elemental anal., IR, mass and NMR (1H and 13C) spectral data. [{InMe2(OC6H4-OxMe2)}2] has a dimeric structure as established by x-ray diffraction. The In atom acquires an irregular trigonal bipyramidal geometry defined by C2O2N ligating atoms. This study involved multiple reactions and reactants, such as 2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol (cas: 163165-91-1Category: oxazolidine).
2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol (cas: 163165-91-1) belongs to oxazolidine derivatives. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries. Oxazolidines are cyclic condensation products of β-amino alcohols and aldehydes or ketone, and they undergo a facile and complete hydrolysis in aqueous solution. Alterations in carbonyl moiety control the rate of formation of a given β-amino alcohol.Category: oxazolidine
163165-91-1;2-(4,4-Dimethyl-4,5-dihydrooxazol-2-yl)phenol;The future of 163165-91-1;New trend of C11H13NO2;function of 163165-91-1