Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 7789-45-9, is researched, SMILESS is [Cu+2].[Br-].[Br-], Molecular Br2CuJournal, Article, Journal of the American Chemical Society called Wavelength-Resolved PhotoATRP, Author is Nardi, Martina; Blasco, Eva; Barner-Kowollik, Christopher, the main research direction is wavelength resolved photochem atom transfer radical polymerization.Electric Literature of Br2Cu.
The careful mapping of photoinduced reversible-deactivation radical polymerizations (RDRP) is a prerequisite for their applications in soft matter materials design. Here, we probe the wavelength-dependent behavior of photochem. induced atom transfer radical polymerization (ATRP) using nanosecond pulsed-laser polymerization (PLP). The photochem. reactivities at identical photon fluxes of Me acrylate in terms of conversion, number-average mol. weight, and dispersity of the resulting polymers are mapped against the absorption spectrum of the copper(II) catalyst in the range of 305-550 nm. We observe a red shift of the action spectrum relative to the absorption spectrum of the copper(II) catalyst. Both the number-average mol. weight and the dispersity show a wavelength dependence, while the mol. weight and conversion remain linearly correlated. The reported data allow the judicious selection of optimum wavelengths for photoATRP.
In addition to the literature in the link below, there is a lot of literature about this compound(Cupric bromide)Electric Literature of Br2Cu, illustrating the importance and wide applicability of this compound(7789-45-9).
Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem