Electric Literature of 13590-42-6, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.13590-42-6, Name is (S)-Benzyl 2-(2,5-dioxooxazolidin-4-yl)acetate, molecular formula is C12H11NO5. In a article,once mentioned of 13590-42-6
Thermoresponsive Alignment Media in NMR Spectroscopy: Helix Reversal of a Copolyaspartate at Ambient Temperatures
Poly(aspartic acid esters) are known to form either right-or left-handed alpha-helices depending on the ester group in the side chain, on solvent and/or on temperature. Polyphenethyl-l-aspartates (PPLA) exhibit a helix reversal from the right- to the left-handed form with increasing temperature. We have recently reported the application of polyphenethylaspartates as helically chiral alignment media. The thermoresponsivity observed for these polymers offers the possibility to measure different orientations of analytes before and after helix reversal of the alignment medium at 373 K. Herein we present a synthesized copolymer of phenethyl- and benzylaspartate as a new alignment medium undergoing this helix reversal at 303?313 K. Thus, the measurement of residual dipolar couplings (RDC) before and after the helix reversal is allowed for at ambient temperatures. A complete sign change of all 1H?13C RDCs was observed, which is close to the highest possible difference in NMR spectra.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 13590-42-6
Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H2419NO – PubChem