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Enantioselective Diels-Alder reactions of 3-(acyloxy)acrylates
Diels-Alder reactions with 3-(acyloxy)acrylates using chiral Lewis acid catalysts have been successfully carried out. These reactions proceed with high enantioselectivity when a chiral Lewis acid derived from Cu(OTf)2 and a bisoxazoline is used. The facility of the reaction is dependent on the nature of the acyloxy group in the dienophile.
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Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H995NO – PubChem