16251-45-9, Name is (4S,5R)-4-Methyl-5-phenyloxazolidin-2-one, belongs to oxazolidine compound, is a common compound. Computed Properties of C10H11NO2In an article, once mentioned the new application about 16251-45-9.
Asymmetric tandem Michael-Aldol reactions between 3-cinnamoyloxazolidine-2- thiones and aldehydes
Reactions between chiral 3-cinnamoyl-4-methyl-5-phenyl-1,3-oxazolidine-2- thiones and aromatic aldehydes in the presence of BF3¡¤Et 2O diastereoselectively produced tricyclic compounds incorporating a bridgehead carbon bound to four heteroatoms in high yields. Four stereocenters were induced during the reaction. The tricyclic products were transformed into propane-1,3-diols bearing three consecutive stereocenters by acid hydrolysis, S-methylation, and reductive removal of the chiral auxiliary.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 16251-45-9
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2177NO – PubChem