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A highly efficient enantioselective total synthesis of the natural antibiotic IKD-8344 is achieved through a convergent route. This route features an otherwise impossible concurrent formation of the THF rings from a linear polyketide precursor through intramolecular O alkylations of mesylates in competition with normally rather facile beta elimination and/or alpha racemization reactions (see scheme, Ms=methanesulfonyl). Copyright
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Oxazolidine – Wikipedia,
Oxazolidine | C3H2273NO – PubChem