Hydrogen bonding to metal β-ketoenolates was written by Davis, T. S.;Fackler, J. P. Jr.. And the article was included in Inorganic Chemistry in 1966.Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) This article mentions the following:
An ir spectral examination of H bonding to various neutral bis, tris, and tetrakis β-ketoenolate complexes were carried out by using deuteriochloroform, H2O, and MeOH as the H-bonding agents. Very weak or no H bonding with the tetrahedral bis complexes, stronger H bonding to the planar bis and to many of the tris complexes, and a pronounced interaction of the solvent with tetrakis complexes are indicated. The H-bond interaction of H2O with acetylacetonatomanganese-(III) and diisobutyrylmethanatomanganese(III) also was examined Sites available for H bonding to the complexes are discussed. In the experiment, the researchers used many compounds, for example, Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)).
Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives.Oxazolidines are readily available also from propargyl amines. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)
Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem