Beyer, Valentin Peter; Cattoz, Beatrice; Becer, Caglar Remzi published the article 《Thiol-Bromo Click Reaction for One-Pot Synthesis of Star-Shaped Polymers》. Keywords: thiol bromo click star shaped polymer; Cu-mediated RDRP; Star polymers; click reactions; one pot reactions; thiol-bromo.They researched the compound: Cupric bromide( cas:7789-45-9 ).Recommanded Product: Cupric bromide. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:7789-45-9) here.
Star-shaped polymers have unique phys. properties and they are sought after materials in industry. However, the ease of synthesis is essential for translation of these materials into large-scale applications. Herein, a highly efficient synthetic method to prepare star-shaped polymers by combination of Cu-mediated reversible deactivation radical polymerization (Cu-RDRP) and thiol-bromo click reaction is described. Well-defined linear and block polymers with a very high bromine chain end fidelity are obtained via Cu-RDRP and subsequently react with multi-functional thiol compounds High coupling efficiencies of larger than 90% are obtained owing to the quick and efficient reaction between thiols and alkyl bromides. Moreover, the arms of the obtained star-shaped polymers are linked via thioether bonds to the core, making them susceptible for oxidative degradation
This compound(Cupric bromide)Recommanded Product: Cupric bromide was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem