Barnes, Dennis A. et al. published their research in Macromolecules in 2003 | CAS: 15214-66-1

Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Recommanded Product: Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)

Addition Polymerization of Norbornene-Type Monomers Using Neutral Nickel Complexes Containing Fluorinated Aryl Ligands was written by Barnes, Dennis A.;Benedikt, George M.;Goodall, Brian L.;Huang, Shyhchang S.;Kalamarides, Heather A.;Lenhard, Susan;McIntosh, Lester H. III;Selvy, K. T.;Shick, Robert A.;Rhodes, Larry F.. And the article was included in Macromolecules in 2003.Recommanded Product: Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) This article mentions the following:

The strong Lewis acid B(C6F5)3 was found to activate complexes of nickel toward the polymerization of norbornene-type monomers. The active species in this reaction is created by the transfer of C6F5 from boron to nickel. As a result, a class of neutral, single-component nickel complexes was developed containing two electron-withdrawing aryl ligands that polymerize norbornene and norbornenes with functional pendant groups. Active complexes include Ni(C6F5)2(PPh2CH2C(O)Ph), (η6-toluene)Ni(C6F5)2, and Ni(2,4,6-tris(trifluoromethyl)phenyl)2(1,2-dimethoxyethane). In the case of (η6-toluene)Ni(C6F5)2, isolation and characterization of low mol. weight norbornene polymers, using ethylene, indicated that each polymer chain contained a C6F5 headgroup. This points to the initiation step as being the insertion of norbornene into the Ni-C6F5 bond. The polymer microstructure as revealed by 1H and 13C NMR spectrometry is entirely different from that produced using the cationic nickel catalyst, [(η3-crotyl)Ni(1,4-COD)]PF6. This difference in microstructure led to improved mech. properties for 80:20 copolymers of norbornene and 5-triethoxysilylnorbornene. In the experiment, the researchers used many compounds, for example, Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1Recommanded Product: Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)).

Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives. Oxazolidines that are the precursor to bisoxazolidines are in effect mono-oxazolidines. They are also used as moisture scavengers in polyurethane and other systems. Chiral oxazolidines are widely used as chiral auxiliaries, chiral ligands, protecting and/or directing groups in a variety of asymmetric transformations, thanks also to their easy cleavage or their further elaboration possibilities.Recommanded Product: Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem

 

Davis, T. S. et al. published their research in Inorganic Chemistry in 1966 | CAS: 15214-66-1

Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives.Oxazolidines are readily available also from propargyl amines. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)

Hydrogen bonding to metal β-ketoenolates was written by Davis, T. S.;Fackler, J. P. Jr.. And the article was included in Inorganic Chemistry in 1966.Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) This article mentions the following:

An ir spectral examination of H bonding to various neutral bis, tris, and tetrakis β-ketoenolate complexes were carried out by using deuteriochloroform, H2O, and MeOH as the H-bonding agents. Very weak or no H bonding with the tetrahedral bis complexes, stronger H bonding to the planar bis and to many of the tris complexes, and a pronounced interaction of the solvent with tetrakis complexes are indicated. The H-bond interaction of H2O with acetylacetonatomanganese-(III) and diisobutyrylmethanatomanganese(III) also was examined Sites available for H bonding to the complexes are discussed. In the experiment, the researchers used many compounds, for example, Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)).

Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II) (cas: 15214-66-1) belongs to oxazolidine derivatives.Oxazolidines are readily available also from propargyl amines. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Quality Control of Bis(2,2′,6,6′-tetramethylheptanedionato) palladium(II)

Referemce:
Oxazolidine – Wikipedia,
Oxazolidine | C3H7NO – PubChem