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General Asymmetric Synthetic Strategy for the alpha-Alkylated 2,5,6-Trisubstituted Pyran of Indanomycin and Related Natural Products
A general synthetic strategy for convergent asymmetric synthesis of C1?C10 fragment of tetraene-containing natural product indanomycin was achieved starting from 2-(benzyloxy)acetaldehyde which in turn was obtained from very inexpensive material cis-1,4-butene-diol. Key steps include Evans’ aldol reaction, HWE olefination, iodine-catalyzed tandem isomerization followed by C?O and C?C bond formation similar to our earlier report in constructing the trans-2,6-disubstituted dihydropyran ring and Evans’ asymmetric alkylation.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: (R)-4-Benzyl-2-oxazolidinone, you can also check out more blogs about102029-44-7
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H1932NO – PubChem