Awesome and Easy Science Experiments about Methyl (R)-N-Boc-2,2-dimethyloxazolidine-4-carboxylate

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Total Synthesis of the Post-translationally Modified Polyazole Peptide Antibiotic Goadsporin

The structurally unique polyazole antibiotic goadsporin contains six heteroaromatic oxazole and thiazole rings integrated into a linear array of amino acids that also contains two dehydroalanine residues. An efficient total synthesis of goadsporin is reported in which the key steps are the use of rhodium(II)-catalyzed reactions of diazocarbonyl compounds to generate the four oxazole rings, which demonstrates the power of rhodium carbene chemistry in organic chemical synthesis.

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Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H2504NO – PubChem