Chemistry, like all the natural sciences, Computed Properties of C16H19NO5, begins with the direct observation of nature¡ª in this case, of matter.84793-24-8, Name is Ethyl (S)-2-[(S)-4-Methyl-2,5-dioxo-3-oxazolidinyl]-4-phenylbutanoate, SMILES is O=C(OCC)[C@@H](N([C@H]1C)C(OC1=O)=O)CCC2=CC=CC=C2, belongs to oxazolidines compound. In a document, author is Bayer, Patrick, introduce the new discover.
Stereoselective Photooxidations by the Schenck Ene Reaction
150 years after the first report of an organic reaction with singlet oxygen (O-1(2)) and 70 years after the discovery of the singlet oxygen-ene reaction (Schenck reaction) with alkenes, this allylic photooxidation has matured to a powerful transformation that enables access to diverse sets of allyl alcohol derivatives from ubiquitous starting materials. The reaction exhibits high sustainability (100% atom economy, use of simple alkenes, air, metal-free catalyst and visible light). Good levels of chemo-, regio-, and stereocontrol were observed in the synthesis of various fine chemical building blocks and biologically active molecules. This Minireview provides an overview of the key strategies that enable stereoselective oxygen-ene reactions in the context of complex molecule syntheses including photooxygenations of functionalized alkenes, cycloalkenes, and auxiliary-based methods.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 84793-24-8. Computed Properties of C16H19NO5.
Reference:
Oxazolidine – Wikipedia,
,Oxazolidine | C3H7NO – PubChem