Archives for Chemistry Experiments of (R)-4-Benzyl-3-(3-methylbutanoyl)oxazolidin-2-one

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A synthesis of the dienone 7 via an efficient intramolecular Stille cross-coupling reaction, an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes using Bu3SnCHI2 in DMF, and a synthesis of the substituted (-)-dienone 25 via ring-closing alkene metathesis to give dihydropyran 22 are described. The synthesis of (-)-dienone 25 constitutes a formal synthesis of (-)-periplanone-B. The Royal Society of Chemistry 1999.

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Reference：
Oxazolidine – Wikipedia,
Oxazolidine | C3H2599NO – PubChem