Chemistry is traditionally divided into organic and inorganic chemistry. SDS of cas: 497-25-6, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 497-25-6
The Dichotomy of Gold-catalyzed Interplay between Cyanamides and Ynamides: Controllable Switch from [2+2+2] to [4+2] Cycloaddition
The gold-catalyzed interplay between cyanamides and ynamides demonstrates condition-dependent mechanistic dichotomy. [2+2+2] Cycloaddition proceeds under kinetically controlled conditions to give 2,4,6-triaminopyrimidines (19 examples, up to 99%). Under thermodynamically controlled conditions, the reactivity switches from [2+2+2]- to [4+2] cycloaddition; the latter [4+2] reaction accomplishes 1,3-diaminoisoquinolines (19 examples, up to 97%). The advantages of both methods include regioselectivity, mild reaction conditions (even for the thermodynamically controlled [4+2] reaction) and the possibility of introducing a variety of dialkyl, diaryl, and heterocyclic amino substituents into the target pyrimidine and isoquinoline cores. The reactions were conducted on gram scales and the versatility of the obtained products was demonstrated by post-functionalizations. (Figure presented.).
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Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H505NO – PubChem