Further Studies on the [1,2]-Wittig Rearrangement of 2-(2-Benzyloxy)aryloxazolines was written by Aitken, R. Alan; Harper, Andrew D.; Inwood, Ryan A.. And the article was included in Molecules in 2022.Formula: C15H13NO2 The following contents are mentioned in the article:
The behavior of 14 ortho-functionalized 2-aryloxazolines (11 of them prepared and characterized for the first time) with butyllithium had been examined Significant limitations to the Wittig rearrangement of such systems were revealed. In terms of asym. Wittig rearrangement, good diastereoselectivity was obtained with a valine-derived 4-iso-Pr oxazoline, but this was compromised by racemization upon hydrolysis. More encouraging selectivity was achieved in the Wittig rearrangement of an acyclic phenylalanine-derived ortho-benzyloxy benzamide. This study involved multiple reactions and reactants, such as (R)-2-(4-Phenyl-4,5-dihydrooxazol-2-yl)phenol (cas: 150699-08-4Formula: C15H13NO2).
(R)-2-(4-Phenyl-4,5-dihydrooxazol-2-yl)phenol (cas: 150699-08-4) belongs to oxazolidine derivatives. Oxazolidine-based compounds have started to attract attention also in the medicinal and materials chemistry fields. Oxazolidines are well known as key portions of bioactive molecules or precursors of chiral molecules, as well as established chiral auxiliaries.Formula: C15H13NO2
150699-08-4;(R)-2-(4-Phenyl-4,5-dihydrooxazol-2-yl)phenol;The future of 150699-08-4;New trend of C15H13NO2;function of 150699-08-4