Final Thoughts on Chemistry for Oxazolidin-2-one

We very much hope you enjoy reading the articles and that you will join us to present your own research about497-25-6 Related Products of 497-25-6

Related Products of 497-25-6, Modeling chemical reactions helps engineers virtually understand the chemistry, optimal size and design of the system, and how it interacts with other physics that may come into play.In a article, mentioned the application of 497-25-6, Name is Oxazolidin-2-one, molecular formula is C3H5NO2

We have evaluated various achiral templates (1a-g, 10, and 16) in conjunction with chiral Lewis acids in the conjugate addition of nucleophilic radicals to alpha-methacrylates followed by enantioselective H-atom transfer. Of these, a novel naphthosultam template (10) gave high enantioselectivity in the H-atomtransfer reactions with ee’s up to 90%. A chiral Lewis acid derived from MgBr2 and bisoxazoline (2) gave the highest selectivity in the enantioselective hydrogen-atom-transfer reactions. Non-C2 symmetric oxazolines (20-25) have also been examined as ligands, and of these, compound 25 gave optimal results (87% yield and 80% ee). Insights into rotamer control in alpha-substituted acrylates and the critical role of the tetrahedral sulfone moiety in realizing high selectivity are discussed.

We very much hope you enjoy reading the articles and that you will join us to present your own research about497-25-6 Related Products of 497-25-6

Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H997NO – PubChem