Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, 6704-31-0, Name is Oxetan-3-one, SMILES is O1CC(C1)=O, belongs to oxazolidines compound. In a document, author is Eswaran, Sambasivan V., introduce the new discover, Name: Oxetan-3-one.
Tuning the strain effect to induce selectivity through intramolecular nitrene insertion into an adjacent methoxy C-H bond leading to form a new benzoxazole: experimental and computational studies
Pyrolysis of azido-meta-meconine yields only a single product 1D, which has been characterized spectro-scopically (H-1 NMR, C-13 NMR, HSQC, DEPT & MS). These results reveal that the fused five-member lactone ring can influence the product selectivity. The DFT calculations suggest the formation of favourable oxazolidine intermediate compared to azirine (1Z) and ketenimine (1H) intermediates. The isodesmic analysis showed that the fused lactone aryl nitrene (1N) would have more strain to form azirine (1Z) intermediate than the corresponding aryl nitrene (1M). (C) 2016 Elsevier Ltd. All rights reserved.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 6704-31-0 is helpful to your research. Name: Oxetan-3-one.
Reference:
Oxazolidine – Wikipedia,
,Oxazolidine | C3H7NO – PubChem