Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, 34052-90-9, Name is 1,3-Bis(4,5-dihydrooxazol-2-yl)benzene, SMILES is C1(C2=NCCO2)=CC=CC(C3=NCCO3)=C1, belongs to oxazolidines compound. In a document, author is Mardani, Zahra, introduce the new discover, Product Details of 34052-90-9.
2D-Coordination polymer containing lead(II) in a hemidirected PbO4S3 environment formed by molecular breaking of the 1,3-oxathiolane ligand
A new 1,3-oxathiolane-based ligand, 2-(1,3-oxathiolan-2-yl)pyridine, was prepared and its coordination to lead(II) was investigated. Experiments revealed a ligand-breaking reaction during the complexation process, which leads to the formation of a 2D-coordination polymer of lead(II), [Pb(mu(3)-HME)(mu-OAc)](n); H2ME: 2-mercaptoethanol. The compounds have been characterized by elemental analysis, FT-IR, H-1 NMR spectroscopy and single-crystal X-ray diffraction. X-ray analysis revealed a 2D-coordination polymer extending via acetato bridges. The lead(II) center adopts a rare PbO4S3-distorted pentagonal bipyramidal geometry with a hemidirected arrangement. Upon coordination, the thiol group of the H2ME ligand is deprotonated to coordinate as an anionic ligand. The network extends in sheets in the crystallographic ab plane via Pb-S-Pb and Pb-O-Pb bridges, aided by O-H center dot center dot center dot O hydrogen bonds.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 34052-90-9 is helpful to your research. Product Details of 34052-90-9.
Reference:
Oxazolidine – Wikipedia,
,Oxazolidine | C3H7NO – PubChem