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(matrix presented) Chiral Lewis acid catalyzed N-benzylhydroxylamine addition to pyrrolidinone-derived enoates afforded beta-aryl-beta-amino acid derivatives in high enantiomeric purity with moderate to very good chemical efficiency.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H993NO – PubChem

 

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A pilot plant campaign was performed to study MEA degradation in CO2 capture conditions and anticipate potential degradation products emissions to the atmosphere in industrial case. Aqueous 30% wt MEA was cycled between absorption and regeneration steps during 1700 h in the presence of a synthetic flue gas containing 81% of N2, 14% of CO2, 5% of O2, 97 ppm of NO, 9 ppm of SO2 and 5 ppm of NO2. Specific methods (sampling, sample conditioning and analysis) were developed to improve degradation products identification and to provide a quantification of targeted compounds in liquid phase and above all in absorber and stripper gas effluents. Especially, trace elements were detected in liquid phase thanks to Head Space-Solid Phase MicroExtraction (HS-SPME) and liquid-liquid extraction with ChemElut cartridges and in gas phase thanks to adsorbent tubes of different type: Sep-Pakfor aldehydes and ketones, Orbo 60 for N-nitrosodimethylamine, Tenax and active charcoal for non-specific adsorption. 32 degradation products were identified in liquid phase and 38 in gas phase, 17 of which for the first time, especially derivatives of pyridine and oxazolidine, 1H-pyrrole and a new nitrosamine, the N-nitroso-2-methyl-oxazolidine.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H410NO – PubChem

 

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Post-combustion Carbon dioxide (CO2) capture (PCC) via amine absorption-stripping is an evolving technology towards mitigation of CO2 emissions. One of the major challenges in the technology development is the suitability of the solvent. Under the process operating conditions, irreversible reactions occur, thereby degrading the amine. The consequences of amine degradation are inevitable. The degradation products are harmful to the environment, increase the corrosion in the process equipment, cause fouling and ultimately make the process inefficient, hazardous and expensive. Monoethanolamine (MEA) is the benchmark solvent used and tested at industrial level for CO2 capture because of its high absorption rate and capacity to capture CO2 as well as medium to high resistance against oxidative and thermal degradation. This review reports degradation of MEA under process operating conditions, which includes up-to-dated list of degradation products, degradation kinetics and degradation pathways. Furthermore, degradation inhibition, computational studies, corrosivity as well as environmental concerns regarding the emissions of amine degradation products are critically reviewed. The objective of study is to provide researchers with a comprehensive knowledge on degradation of MEA, ways to reduce degradation, corrosion inhibition and understanding of environmental concerns for development of models for better understanding of behaviour of MEA and knowledge gaps.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H946NO – PubChem

 

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An efficient construction of a suitably functionalized trisoxazole derivative related to telomestatin was developed from L-serine, which involved three sequential oxazoline cyclization-oxidation steps in an overall yield of 11% in a linear sequence of twelve steps. Georg Thieme Verlag Stuttgart.

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Oxazolidine – Wikipedia,
Oxazolidine | C3H2496NO – PubChem

 

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Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. Computed Properties of C3H5NO2. Introducing a new discovery about 497-25-6, Name is Oxazolidin-2-one

Compounds of formula (I) and pharmaceutically acceptable salts thereof are provided: wherein R1, m, X, R2, n, W, p, Y, Z, R3, R4, R5 and q have the meanings as defined in the description. Methods of preparation and uses thereof in therapy, particularly for CNS disorders such as depression or anxiety, are also disclosed.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H32NO – PubChem

 

Sep-21 News More research is needed about 1192-07-0

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SDS of cas: 1192-07-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1192-07-0, Name is Isoxazolidin-3-one, molecular formula is C3H5NO2. In a Patent,once mentioned of 1192-07-0

Compounds of the formula (I), wherein the substituents are as defined in claim 1, useful as a pesticides, especially as fungicides.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H1222NO – PubChem

 

S-21 News Properties and Exciting Facts About 695-53-4

Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.Read on for other articles about 695-53-4

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The currently known methods for the synthesis of hydrogenated derivatives of synthetic porphyrins-chlorins, bacteriochlorins, isobacteriochlorins and their tetraaza analogues-are considered. Reactions involving quasi-isolated double bonds including reduction, oxidative addition and cycloaddition are presented. Examples of direct synthesis of these macroheterocycles are given.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H1355NO – PubChem

 

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The intramolecular Diels-Alder adduct 12 was converted via dimesylate 20 into dienone 7, which represents the unusual, and apparently quite stable, core of the antitumor agent ottelione B (1).

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Oxazolidine – Wikipedia,
Oxazolidine | C3H447NO – PubChem

 

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Several new methods for the synthesis of differently substituted 2-amidofurans are described. The thermolysis of furan-2-carbonyl azide results in a Curtius rearrangement and the resulting furanyl isocyanate was trapped with various organometallic reagents. A second method consists of a C-N cross-coupling reaction of a bromo-substituted furan with various amides, carbamates, and lactams. The CuI-catalyzed cross-coupling reaction between furanyl bromides and amides furnished 2- and 3-substituted amidofurans in 45-95% yield. The third protocol used involves the reaction of cyclic carbinol amides with triflic anhydride. The reaction proceeds under very mild conditions to provide alpha-(trifluoromethyl)sulfonamido-substituted furans in high yield. The resulting iminium ion derived from the reaction of the hydroxy pyrrolidinone with Tf2O undergoes a facile ring opening as a consequence of the adjacent hydroxyl group to produce an imino triflate intermediate. Subsequent cyclization of this highly electrophilic imine with the oxygen atom of the adjacent carbonyl group leads to an imino dihydrofuran that reacts further with another equivalent of Tf2O to give the observed product.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H879NO – PubChem

 

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Organic electrosynthesis has received great attention as a powerful green tool for synthesis, affording less waste production, less chemicals spent, and often fewer reaction steps than conventional methods. Functional group interconversion and C-C bond generation by imposition of a proper electrode potential is what lies behind organic electrosynthesis processes. Paired electrochemical reactions, indirect electrosynthesis, electrochemical microreactors, and the use of ionic liquids are some of the highlighted means that contribute to optimization of the overall process. Necessity to use specific organic solvents combined with supporting electrolytes is one of the main limitations to be overcome to make the electrochemical process more economically feasible when compared to nonelectrochemical processes. Numerous examples from the bench scale to industrial routes such as adiponitrile, substituted benzaldehydes, anthraquinone, fluorinated products, and succinic acid production are well described throughout this review.

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Reference:
Oxazolidine – Wikipedia,
Oxazolidine | C3H400NO – PubChem