Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 497-25-6. In my other articles, you can also check out more blogs about 497-25-6
Reference of 497-25-6, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 497-25-6, Oxazolidin-2-one, introducing its new discovery.
Photoreduction of aryl ketones by amides, lactams and various nitrogen-containing heterocycles
Benzophenone is photoreduced by amides and lactams.The hydrogen atom alpha to the nitrogen atom is abstracted regioselectively; coupling of the two resulting radicals leads to adducts with a 1-phenylethanolamide structure.The use of this general reaction in synthetic reactions is demonstrated: adducts of benzophenone with amides, lactams, 2,4-imidazolinediones, tetrahydro-2H-1,3-oxazin-2-one and 2-oxazolidinone, and of dibenzosuberone, 9H-xanthenone, 9H-thioxanthenone and alpha-tetralone with 1-methyl-2-pyrrolidinone, N,N-dimethylacetamide and N,N-diethylacetamide are described.Kinetic parameters for dibenzosuberone and 9H-thioxanthenone are given.Knowledge of the rate constants of photoreduction (kr) and autodeactivation (kTa) allows optimization of the experimental procedure to provide adducts in good yields.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 497-25-6. In my other articles, you can also check out more blogs about 497-25-6
Reference£º
Oxazolidine – Wikipedia,
Oxazolidine | C3H567NO – PubChem